Abstract
Partial to particular particles: The morphology of the polymer particles can be controlled in ethylene/CO copolymerization by pressurizing catalyst-containing 1-octanol droplets dispersed in water. The palladium catalyst should be harnessed with lipophilic long alkyl chains. Polymer particles of 0.5-1.0 mm size (see micrographs) with bulk densities of 0.2-0.3 g mL-1 are produced without reactor fouling. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Park, J. H., Oh, K. H., Kim, S. H., Cyriac, A., Varghese, J. K., Hwang, M. W., & Lee, B. Y. (2011). Morphology control of polymer particles in ethylene/carbon monoxide copolymerization. Angewandte Chemie - International Edition, 50(46), 10932–10935. https://doi.org/10.1002/anie.201105270
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