2-[(4-Methylphenyl)sulfanyl]aniline

Abstract

The leastsquares planes defined by the aromatic moieties in the title aniline derivative, C13H13NS, are nearly perpendicular to each other, forming a dihedral angle of 87.80 (7)°. Apart from a weak intramolecular N -H⋯S hydrogen bond, a cooperative set of N -H⋯N hydrogen bonds present in the crystal structure leads to the formation of tetrameric units.