Cobalt(II) and Manganese(II) Complexes of Novel Schiff Bases, Synthesis, Charcterization, and Thermal, Antimicrobial, Electronic, and Catalytic Features

Abstract

Carbazoles containing two new Schiff bases (Z,Z)-N,N′-bis[(9-ethyl-9 H -carbazole-3-yl)methylene]propane-1,3 diamine (L 1 ) and (Z,Z)-N,N′-bis[(9-ethyl-9 H -carbazole-3-yl)methylene]-2,2-dimethylpropane-1,3-diamine (L 2 ) and their Co(II) and Mn(II) complexes were synthesized and characterized using various spectroscopic methods and thermal analysis, which gave high thermal stability results for the ligands and their cobalt complexes. The title compounds were examined for their antimicrobial and antifungal activities, which resulted in high activity values for the ligands and their manganese complexes. Oxidation reactions carried out on styrene and cyclohexene revealed that the complex compounds were the most effective catalysts for styrene oxidation, giving good selectivities than those of cyclohexene oxidation. Electronic features of the synthesized compounds were also reported within this work.