Abstract
Three new chiral Mn macrocycle catalysts containing 20 or 40 atoms in the macrocy-cle were synthetized and tested in the enantioselective epoxidation of cis-β-ethyl-styrene and 1,2-dihydronathalene. The effect of the presence of a binaphtol (BINOL) compound in the catalyst backbone has been evaluated, including by Density Functional Theory (DFT) calculations.
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Pappalardo, A., Ballistreri, F. P., Toscano, R. M., Chiacchio, M. A., Legnani, L., Grazioso, G., … Trusso Sfrazzetto, G. (2021). Alkene epoxidations mediated by mn-salen macrocyclic catalysts. Catalysts, 11(4). https://doi.org/10.3390/catal11040465
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