The Effect of Al Doping on Structural, Electrical and Optical Properties of CdSe Films

  • Suha A. Najim
  • Nawfal Y. Jamil
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Abstract

CdSe thin films were deposited on glass substrates by chemical bath deposition technique. The deposited CdSe thin films were annealed by thermal evaporation for (1h) at 250˚C250˚C. The samples were then coated with a different thicknesses of thin Al films (50, 100, 150, 200) Å by thermal evaporation method which then annealed at (1h,250˚C). The structural, optical, and electrical properties of deposited and doped samples were studied. The X-ray diffraction analysis showed that the films have polycrystalline structure of hexagonal type. From optical properties, the band gap energy of undoped CdSe thin film was 2 eV and it is decreased by increasing of Al doping. Electrical resistivity of the doped films showed a decrease with the increase of the Al concentration. The doped and undoped samples revealed that the conductivity was n-type. Keywords: CdSe thin film, Al doping, optical properties, semiconductor ‫ـــــــــــــــــــــــــــــــــــــــــــــ‬ ‫ــــ‬ ‫ــــــــــــ‬ ‫ـــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــ‬ ‫ـــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــ‬ ‫ــــــــــــــــــــــــ‬ ‫ـ‬ ‫تطعيم‬ ‫تأثير‬ Al ‫الخواص‬ ‫على‬ ‫التركيبية‬ ، ‫ألغشية‬ ‫والبصرية‬ ‫الكهربائية‬ CdSe ‫الملخص‬ ‫أغشية‬ ‫ترسيب‬ ‫تم‬ CdSe ‫أرضية‬ ‫على‬ ‫قيقة‬ ‫الر‬ ‫الكيميائي‬ ‫بالحمام‬ ‫الترسيب‬ ‫تقنية‬ ‫باستخدام‬ ‫الزجاج‬ ‫من‬ Chemical Bath Deposition CBD)) ‫أغشية‬. CdSe ‫تلدينها‬ ‫تم‬ ‫المرسبة‬ ‫قيقة‬ ‫الر‬ ‫عند‬ ‫ساعة‬ ‫لمدة‬ ‫اري‬ ‫الحر‬ ‫بالتبخير‬ 250˚C250˚C. ‫تم‬ ‫العينات‬ ‫تطعيمها‬ ‫من‬ ‫بغشاء‬ ‫األلمنيوم‬ ‫قيق‬ ‫الر‬ ‫مختلفة‬ ‫وبأسماك‬ Å (50, 100, 150, 200 ‫اري‬ ‫الحر‬ ‫التبخير‬ ‫يقة‬ ‫بطر‬) ‫ت‬ ‫وبعدها‬ ‫تلدينها‬ ‫م‬ ‫عن‬ ‫د‬ (1h, 250˚C). ،‫التركيبية‬ ‫اص‬ ‫الخو‬ ‫اسة‬ ‫در‬ ‫تم‬ ‫ال‬ ‫بائية‬ ‫الكهر‬ ‫و‬ ‫ية‬ ‫بصر‬ ‫للنماذج‬ ‫المرسبة‬ .‫المطعمة‬ ‫و‬ ‫تبين‬ ‫السينية‬ ‫األشعة‬ ‫حيود‬ ‫تحليل‬ ‫من‬ ‫السداسي‬ ‫النوع‬ ‫من‬ ‫ات‬ ‫البلور‬ ‫متعدد‬ ‫تركيبا‬ ‫تمتلك‬ ‫األغشية‬ ‫بان‬ (Hexagonal .) ‫و‬ ‫من‬ ‫ية‬ ‫البصر‬ ‫اص‬ ‫الخو‬ ‫الطاقة‬ ‫فجوة‬ ‫أن‬ ‫وجد‬ ، ‫ألغشية‬ CdSe ‫المطعمة‬ ‫غير‬ 2 eV ‫نها‬ ‫ا‬ ‫و‬ ‫التطعيم‬ ‫يادة‬ ‫ز‬ ‫مع‬ ‫تقل‬ ‫باأللمنيوم‬. ‫تقل‬ ‫أنها‬ ‫تبين‬ ‫المطعمة‬ ‫لألغشية‬ ‫بائية‬ ‫الكهر‬ ‫المقاومية‬ ‫تركيز‬ ‫يادة‬ ‫ز‬ ‫مع‬ Al. ‫المطعمة‬ ‫النماذج‬ ‫و‬ ‫السالب‬ ‫النوع‬ ‫من‬ ‫توصيلية‬ ‫أظهرت‬ ‫المطعمة‬ ‫غير‬ (n-type) .

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APA

Suha A. Najim, & Nawfal Y. Jamil. (2018). The Effect of Al Doping on Structural, Electrical and Optical Properties of CdSe Films. Rafidain Journal of Science, 27(2), 164–172. https://doi.org/10.33899/rjs.2018.145400

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