Thermoinduced structural-transformation and thermochromic luminescence in organic manganese chloride crystals

Abstract

The [Mn2Cl9]5- mode of red emissive (C4NOH10)5Mn2Cl9·C2H5OH under thermal treatment will be cleaved into [MnCl4]2- in the green emissive (C4NOH10)2MnCl4 with the departure of ethanol. The rapid conversion of luminescence from red to green provides new insight into the luminescence origin and thermal stability of organic-inorganic metal halide hybrids.