(2R,3R)-2,3-dibenzyloxy-1,4-bis(diphenyl-phosphino)butane

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Abstract

The crystal structure of the title compound, C42H40O2P2, an open-chain diphosphine, is reported. The absolute structure determined by the Flack method [Flack (1983). Acta Cryst. A39, 876-881] confirms that the stereochemistry at the chiral centers is (2R,3R). The dihedral angles between the two rings bonded to each phosphine group are 70.94 (10) and 70.20 (10)°, and the angle between the rings of the benzyloxy groups is 59.31 (13)°.

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Matos Beja, A., Paixão, J. A., Ramos Silva, M., Alte Da Veiga, L., Rocha Gonsalves, A. M. A. D. A., Pereira, M. M., & Elisa Silva Serra, M. (1998). (2R,3R)-2,3-dibenzyloxy-1,4-bis(diphenyl-phosphino)butane. Acta Crystallographica Section C: Crystal Structure Communications, 54(2), 264–266. https://doi.org/10.1107/S0108270197014248

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