Pentakis(lprolinium) dodecatungstoborate trihydrate

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Abstract

The title polyoxometalate-based organic-inorganic hybrid compound, (C 5H10NO2)5[BW12O40] ·3H2O, consists of one -Keggin-type [BW12O 40]5- polyoxoanion, five crystallographically independent l-prolinium cations and three uncoordin-ated water mol-ecules. The polyoxoanion shows characteristic features with respect to bond lengths and angles. Several N - H⋯O and O - H⋯O hydrogen bonds between the organic cations, inorganic anions and crystal water mol-ecules lead to a three-dimensional supra-molecular structure.

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Raissi Shabari, A., Pourayoubi, M., & Ghamari, D. (2009). Pentakis(lprolinium) dodecatungstoborate trihydrate. Acta Crystallographica Section E: Structure Reports Online, 65(12). https://doi.org/10.1107/S1600536809047357

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