Abstract
Treatment of the imine PhC(NSiMe3)py with Et2BOMe or BF3·Et2O afforded bicyclic ketiminoboranes 4a and 4bvia intramolecular N-coordination. The basicity of the imine N is evidenced by their reactivity towards Brønsted and Lewis acids and the structures of 4a·HCl and 4b·BF3 are reported as well as the dipyridyl imine derivative 4c·HCl.
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CITATION STYLE
APA
Bacon, C. E., Mansour, L., Hayward, J. J., & Rawson, J. M. (2015). Intramolecular N-coordination in ketiminoboranes. Dalton Transactions, 44(12), 5284–5287. https://doi.org/10.1039/c5dt00196j
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