Positive Eu anomaly development during diagenesis of the K/T boundary ejecta layer in the Agosta section (SE Spain): Implications for trace-element remobilization

Abstract

K/T boundary geochemical anomalies have been used previously to support the impact event at the end of the Cretaceous. However, impact models and assessment of the extraterrestrial contribution to the boundary sediments should also consider the diagenetic alteration of the impact signatures. Mineralogical and geochemical studies centring on redox proxies reveal differences in trace-element concentrations at Agost and Caravaca (SE Spain), two of the most complete K/T boundary sections. These differences probably derive from variations in the diagenetic evolution of the ejecta layer. Several redox proxies, such as extensive pyrite formation, high authigenic uranium concentration and positive Eu anomalies, indicate very strong reducing conditions at Agost. Positive Eu anomalies are extremely unusual in sediments, and in this case are interpreted to indicate a highly reducing environment. In such conditions, certain trace elements such as lr, may have been remobilized, thereby masking the original signature of the impact.