Field-Based, Non-Destructive, and Rapid Detection of Pesticide Residues on Kumquat (Citrus japonica) Surfaces Using Handheld Spectrometer and 1D-ResNet

Abstract

With growing consumer concerns about food safety, developing methods for the field-based, non-destructive, and rapid detection of pesticide residues is becoming increasingly critical. This study introduces a field-based, non-destructive, and rapid method for detecting pesticide residues on kumquat surfaces. Initially, spectral data from the visible/near-infrared (VNIR) light bands were collected using a handheld spectrometer from kumquats treated with three pesticides at various gradient concentrations and water. The data were then preprocessed and analyzed using machine learning (SPA-SVM) and deep learning models (1D-CNN, 1D-ResNet) to determine the optimal model. Features from the convolutional layer of the 1D-ResNet model were extracted for visualization and analysis, highlighting significant differences in features between the different pesticides and across varying concentrations. The results indicate that the 1D-ResNet model achieved 97% overall accuracy, with a macro average of 0.96 and a weighted average of 0.97, and that precision, recall, and F1-score approached 1.00 for most pesticide treatment gradients. The results of this research verified the feasibility of the handheld spectrometer combined with 1D-Resnet for the detection of pesticide residues on the surface of kumquat, realized the visualization of pesticide residue characteristics, and also provided a reference for the detection of pesticide residues on the surface of other fruits.