Influence of Wurtzite ZnO Morphology on Piezophototronic Effect in Photocatalysis

Abstract

A piezoelectric field promotes the photocatalytic activity of a photocatalyst by helping separating photo-generated charge carriers. Wurtzite phase ZnO is a typical photocatalyst with a piezoelectric property, thus self-assisted photocatalysis with ZnO based on the piezophototronic effect can be achieved. ZnO nanorods or nanowires with a clear c-axis have been well studied, while other morphologies have not been fully discussed. In this work, we prepared wurtzite phase ZnO with four different morphologies. By comparing their photocatalytic activity for degradation of Rhodamine B under the same mechanical energy source provided by ultrasound, the effect of morphology and exposed facets on photo-induced charge separation were highlighted. The ZnO nanowire photocatalyst delivered an impressive improvement in photocatalytic efficiency when ultrasound driven, suggesting that the morphology-related piezophototronic effect had a positive effect on separation of photo-generated charge carriers, and more exposed active facets benefitted the utilization of charge carriers.