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Enantioselective synthesis of pachastrissamine (Jaspin B) using dirhodium(II)-catalyzed C-H amination and asymmetric dihydroxylation as key steps

Chemical and Pharmaceutical Bulletin (2007) 55(8) 1284-1286
DOI: 10.1248/cpb.55.1284
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Abstract

Enantioselective total synthesis of anhydrophytosphingosine pachastrissamine (jaspin B) was achieved using Sharpless asymmetric dihydroxylation and dirhodium(II)-catalyzed C-H amination as key steps. © 2007 Pharmaceutical Society of Japan.

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Yakura, T., Sato, S., & Yoshimoto, Y. (2007). Enantioselective synthesis of pachastrissamine (Jaspin B) using dirhodium(II)-catalyzed C-H amination and asymmetric dihydroxylation as key steps. Chemical and Pharmaceutical Bulletin, 55(8), 1284–1286. https://doi.org/10.1248/cpb.55.1284

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