Abstract
A high pressure single crystal X-ray diffraction and Raman spectroscopy study has revealed a similar mechanism for both thermal and pressure-induced spin crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine) and the concomitant anion order-disorder transition.
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Shepherd, H. J., Tonge, G., Hatcher, L. E., Bryant, M. J., Knichal, J. V., Raithby, P. R., … Teat, S. J. (2016). A high pressure investigation of the order-disorder phase transition and accompanying spin crossover in [fel12](Clo4)2 (l1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine). Magnetochemistry, 2(1). https://doi.org/10.3390/magnetochemistry2010009
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