Synthesis of Heterobimetallic Gold(I) Palladium(II) Bis(acyclic diaminocarbene) Complexes via the Isonitrile Route

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Abstract

A convenient one-pot approach to bridged heterobimetallic gold(I) palladium(II) bis(acyclic diaminocarbene) complexes is presented. The methodology exploits the graduated nucleophilicities of aliphatic and aromatic amines connected via an aromatic unit. This enables a straightforward access to bridged complexes from easily available isonitrile metal precursors.

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Dietl, M. C., Vethacke, V., Keshavarzi, A., Mulks, F. F., Rominger, F., Rudolph, M., … Hashmi, A. S. K. (2022). Synthesis of Heterobimetallic Gold(I) Palladium(II) Bis(acyclic diaminocarbene) Complexes via the Isonitrile Route. Organometallics, 41(6), 802–810. https://doi.org/10.1021/acs.organomet.2c00021

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