Reaction of acetoxysilanes with hydroxy compounds

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Abstract

Tetraacetoxysilane reacts with hexanol, cyclohexanol, and phenol to give products of complete or partial replacement of the acetoxy groups. The rate of hydrolysis of the SiOR group in alkoxy(phenoxy)-silanes and alkoxy(phenoxy)acetoxysilanes in homogeneous (THF) and heterogeneous media (on cellulose surface) increases in the series ≡Si-OC6H5 > ≡Si-OC6H13 > ≡Si-OC6H11. ©2001 MAIK "Nauka/Interperiodica".

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Kopylov, V. M., Kireev, V. V., Ivanov, V. V., Astaf’ev, G. Y., & Kozlov, Y. V. (2001). Reaction of acetoxysilanes with hydroxy compounds. Russian Journal of General Chemistry, 71(12), 1924–1928. https://doi.org/10.1023/a:1014244427477

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