Iridium(iii)-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers

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Abstract

Cyclometallated iridium(iii) complexes with 2-phenylpyridine [Ir(ppy)2(CNR)Cl] (ppy = (2-phenylpyridinato-C2,N), R = Xyl, Mes), [Ir(ppy)2(CNR)2](OTf) (R = Xyl, Mes), and fac-[Ir(ppy)3] catalyse the cross-linking of polysiloxanes exclusively at temperatures above 100 °C leading to luminescent rubbers.

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Islamova, R. M., Dobrynin, M. V., Vlasov, A. V., Eremina, A. A., Kinzhalov, M. A., Kolesnikov, I. E., … Luzyanin, K. V. (2017). Iridium(iii)-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers. Catalysis Science and Technology, 7(24), 5843–5846. https://doi.org/10.1039/c7cy02013a

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