Michelson Interferometric Hydrogen Sulfide Gas Sensor Based on NH2-rGO Sensitive Film

Abstract

A highly sensitive hydrogen sulfide gas sensor based on NH2-rGO-coated thin-core-fibre (TCF) Michelson interferometer (MI) is proposed and evaluated. Two sections of TCFs are alternately sandwiched between three single-mode-fibres (SMFs). A Faraday rotator mirror (FRM) is fixed to the end of the last SMF to reflect the light signal and enhance the interference. Then the structure SMF-TCF-SMF-TCF-SMF-FRM (STSTS-F) is successfully constructed. NH2-rGO, as sensing film, is coated on two TCFs and is used to detect traces of hydrogen sulfide gas. Raman spectra and XPS analysis show that NH2-rGO has been successfully synthesised. The thickness of the NH2-rGO film coated on the TCF surface is about 500 nm. By introducing 0-60 ppm hydrogen sulfide gas into the chamber, with the increase in concentration of the gas, the monitoring trough exhibits a blue shift. Our experimental results show that the sensor has good linearity (R2 = 0.98096) and selectivity for hydrogen sulfide gas. The sensitivity is 21.3 pm/ppm, and the response and recovery times are about 72 and 90 s, respectively. The sensor has the advantages of high sensitivity, high selectivity, and small size, enabling the detection of trace hydrogen sulfide in toxic gas environments.