Leuco-Based Composite Resin Dosimeter Film

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Abstract

A polystyrene (PS)-based composite resin dosimeter (CRD) film comprising 2-(phenylamino)-6-(dipentylamino)-3-methylspiro[9H-xanthene-9,3′-phthalide] (Black305) fluoran leuco dye, cerium-doped yttrium aluminum perovskite YAlO3:Ce (YAP:Ce) scintillator, and 2-(4-methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine (MBTT) photoacid generator was developed for the visualization of X-ray exposure doses in the range of 18-170 Gy. The color of the CRD film changed from yellow to black within this range based on the X-ray exposure dose. A CRD film based on Black305/YAP:Ce/MBTT/PS could be used to produce a dosimeter with various color change sensitivities by controlling the thermodynamic parameters of the constituent materials. A CRD film is a promising tool for measuring the X-ray exposure dose and can be used as an alternative to the existing radiochromic dosimeters.

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Iwata, T., Kinashi, K., Doan, H. N., Vo, P. P., Sakai, W., & Tsutsumi, N. (2019). Leuco-Based Composite Resin Dosimeter Film. ACS Omega, 4(6), 9946–9951. https://doi.org/10.1021/acsomega.9b00435

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