High-pressure synthesis of novel lithium niobate-type oxides

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Abstract

We found that two lithium niobate-type oxides, CdPbO3 and PbNiO3 were synthesized by high-pressure as metastable low-pressure perovskite-type phases. We then discussed the stability of lithium niobate-type and perovskite-type oxides relative to oxides with other structure for ABO 3 compounds. Consequently, the tolerance factor of perovskite is not the only predominant one to determine the stability and the crystal field effects of 3d transition metal ions are also important. © 2010 IOP Publishing Ltd.

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Inaguma, Y., Yoshida, M., Tsuchiya, T., Aimi, A., Tanaka, K., Katsumata, T., & Mori, D. (2010). High-pressure synthesis of novel lithium niobate-type oxides. In Journal of Physics: Conference Series (Vol. 215). https://doi.org/10.1088/1742-6596/215/1/012131

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