Synthesis of sterically encumbered 2,9-diaryl substituted phenanthrolines. Key building blocks for the preparation of mixed (bis-heteroleptic) phenanthroline copper(I) complexes

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Abstract

The preparation of several novel 2,9-diaryl phenanthrolines is described. Depending on the steric shielding the formation of bis-homoleptic phenanthroline copper(I) complexes can be suppressed and mixed phenanthroline complexes can be prepared.

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Schmittel, M., Lüning, U., Meder, M., Ganz, A., Michel, C., & Herderich, M. (1997). Synthesis of sterically encumbered 2,9-diaryl substituted phenanthrolines. Key building blocks for the preparation of mixed (bis-heteroleptic) phenanthroline copper(I) complexes. Heterocyclic Communications, 3(6), 493–498. https://doi.org/10.1515/HC.1997.3.6.493

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