Impacts of groundwater extraction on groundwater flow and arsenic distribution in the western Hetao Basin, Inner Mongolia, China

Abstract

Temporal variations in water levels are crucial for understanding As behaviour in groundwater systems. Groundwater levels were recorded in irrigation wells in non-irrigation and irrigation seasons. Groundwater samples were collected yearly in irrigation wells from 2014 to 2016 and in a multilevel well from 2015 to 2016 for analysing geochemical parameters. Results showed that groundwater flow direction was reversed due to groundwater pumping. The change of groundwater flow led to the surface water, as a new groundwater recharge source, which flushed the near-surface sediments enriched in soluble components and increased groundwater TDS. The labile organic matter introduced by the surface water recharge fueled dissimilatory reduction of Fe(III) oxides and further increased groundwater As concentration.