Effect of pH on SILAR deposited CTS thin films

Abstract

Copper tin sulphide thin films have been prepared using successive ionic layer adsorption and reaction method on soda lime glass substrate. In this work cationic precursor solution bath contains copper chloride, tinchloride, triethanolamine and anionic precursor solution contains thioacetamide respectively for the deposition of thin films. The prepared films were characterized by X-ray diffraction spectroscopy (XRD), UV-Vis NIR spectroscopy, scanning electron microscopy(SEM) and energy dispersive analysis(EDS). Average crystalline size calculated using Debye-Scherrer formula is 65.59nm for CTS1 and 71.17nm for CTS2. Band gap of CTS1 is 1.899ev and that of CTS2 is 1.647ev. The band gaps are suited for solar cell applications.