Glass-Forming Ability, Chemical Durability, and Structural Properties of Lead Dioxide-Silicate Glass System

Abstract

The present study aimed to test the solubility of SiO2 in a PbO2 host glass matrix. The new glass system with chemical composition xSiO2∙(100-x)∙PbO2 (in mol%) was obtained at low temperature using the melt-quenching technique. The method proposed for the characterization of the glass system includes X-ray diffraction (XRD), Differential Scanning Calorimetry (DSC), inductively coupled plasma mass spectrometry (ICP-Ms), Fourier Transform Infrared (FTIR), and Electron Spin Resonance (ESR) spectroscopy. Understanding the relationship between the oxide composition, structure, chemical durability, and thermal characteristics of obtained materials is essential for further developing the new glass crystalline material (GCM) compositions with specific desired properties.