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Catalytic enantioselective fluorination of α-chloro-β-keto esters in the presence of chiral nickel complexes

Advanced Synthesis and Catalysis (2010) 352(16) 2783-2786
DOI: 10.1002/adsc.201000515
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Abstract

The catalytic enantioselective electrophilic fluorination promoted by chiral nickel complexes is described. The treatment of α-chloro-β- keto esters with Selectfluor under mild reaction conditions afforded the corresponding fluorinated α-chloro-β-keto esters with excellent enantioselectivities (up to 99% ee). © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Kang, S. H., & Kim, D. Y. (2010). Catalytic enantioselective fluorination of α-chloro-β-keto esters in the presence of chiral nickel complexes. Advanced Synthesis and Catalysis, 352(16), 2783–2786. https://doi.org/10.1002/adsc.201000515

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