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Visible light-mediated difluoroalkylation of electron-deficient alkenes

Beilstein Journal of Organic Chemistry (2018) 14 1637-1641
DOI: 10.3762/bjoc.14.139
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Abstract

A method for the reductive difluoroalkylation of electron-deficient alkenes using 1,1-difluorinated iodides mediated by irradiation with blue light is described. The reaction involves radical addition of 1,1-difluorinated radicals at the double bond followed by hydrogen atom transfer from sodium cyanoborohydride.

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Supranovich, V. I., Levin, V. V., Struchkova, M. I., Hu, J., & Dilman, A. D. (2018). Visible light-mediated difluoroalkylation of electron-deficient alkenes. Beilstein Journal of Organic Chemistry, 14, 1637–1641. https://doi.org/10.3762/bjoc.14.139

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