Abstract
A detailed NMR-spectroscopic study of the multiply 13C-labeled cuprate π complexes 2, 2a and 2b was carried out. The 13C,13C coupling constants observed were interpreted in terms of a deformation of the cuprate-alkene complex from the expected idealized square plane. This conclusion is in agreement with NOESY and ROESY data acquired with unlabeled material. © Wiley-VCH Verlag GmbH, 2001.
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Canisius, J., Mobley, T. A., Berger, S., & Krause, N. (2001). Mechanism of 1,6-addition reactions of organocuprates: Detailed NMR spectroscopic study of a cuprate - Enyne π complex. Chemistry - A European Journal, 7(12), 2671–2675. https://doi.org/10.1002/1521-3765(20010618)7:12<2671::AID-CHEM26710>3.0.CO;2-S
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