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Palladium-catalyzed oxidative regio- and diastereoselective diarylating carbocyclization of dienynes

Chemistry - A European Journal (2013) 19(21) 6571-6575
DOI: 10.1002/chem.201204555
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Abstract

Transmetallation: A highly regio- and diastereoselective carbocyclization involving a palladium-catalyzed 1,2-addition of two carbon atoms across a conjugated diene has been developed (see scheme). The reaction is performed with dienynes and an oxygen tether containing a terminal or internal triple bond. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Jiang, M., & Bäckvall, J. E. (2013). Palladium-catalyzed oxidative regio- and diastereoselective diarylating carbocyclization of dienynes. Chemistry - A European Journal, 19(21), 6571–6575. https://doi.org/10.1002/chem.201204555

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