Review of Modified Nickel-Cobalt Lithium Aluminate Cathode Materials for Lithium-Ion Batteries

Abstract

Ternary nickel-cobalt lithium aluminate LiNixCoyAl1-x-yO2 (NCA, x≥0.8) is an essential cathode material with many vital advantages, such as lower cost and higher specific capacity compared with lithium cobaltate and lithium iron phosphate materials. However, the noticeably irreversible capacity and reduced cycle performance of NCA cathode materials have restricted their further development. To solve these problems and further improve the electrochemical performance, numerous research studies on material modification have been conducted, achieving promising results in recent years. In this work, the progress of NCA cathode materials is examined from the aspects of surface coating and bulk doping. Furthermore, future research directions for NCA cathode materials are proposed.