Distinct photochemistry in glycine particles mixed with different atmospheric nitrate salts

Abstract

Particulate free amino acids (FAAs) are essential components of organonitrogen that have critical climate impacts, and they are usually considered stable end-products from protein degradation. In this work, we investigated the decay of glycine (GC) as a model FAA under the photolysis of different particulate nitrate salts using an in situ Micro-Raman system. Upon cycling the relative humidity (RH) between 3g¯% and 80g¯% RH, ammonium nitrate (AN) and GC mixed particles did not exhibit any phase change, whereas sodium nitrate (SN) and GC mixed particles crystallized at 60g¯% and deliquesced at 82g¯% RH. Under light illumination at 80g¯% RH, ANg¯+g¯GC particles showed almost no spectral changes, while rapid decays of glycine and nitrate were observed in SNg¯+g¯GC particles. The interactions between nitrate and glycine in ANg¯+g¯GC particles suppressed crystallization but also hindered nitrate photolysis and glycine decay. On the other hand, glycine may form a complex with Na+ in deliquescent SNg¯+g¯GC particles and allow unbonded nitrate to undergo photolysis and trigger glycine decay, though nitrate photolysis was greatly hindered upon particle crystallization. Our work provides insights into how FAAs may interact with different nitrate salts under irradiation and lead to distinct decay rates, which facilitates their atmospheric lifetime estimation.