New Ni4Na2-phenylgermsesquioxane architecture: Synthesis, structure and slow dynamic behaviour

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Abstract

The first Ni(ii)-based metallagermaniumsesquioxane cage compound [(PhGeO1.5)10(NiO)4(NaO0.5)2] presents a sandwich-like structure where two germsesquioxane cages are linked through an {NiO}4 core and exhibits slow dynamics of the magnetization.

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Kulakova, A. N., Bilyachenko, A. N., Korlyukov, A. A., Long, J., Levitsky, M. M., Shubina, E. S., … Larionova, J. (2018). New Ni4Na2-phenylgermsesquioxane architecture: Synthesis, structure and slow dynamic behaviour. Dalton Transactions, 47(20), 6893–6897. https://doi.org/10.1039/c8dt00900g

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