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Novel carbon-carbon bond oxidative cleavage of hexabenzyl-hexaazaisowurtzitane by n-BuONO and (NH4)2Ce(NO3)6

Molecules (1999) 4(3) 69-72
DOI: 10.3390/40300069
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Abstract

Treatment of 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12-hexaazatetracyclo-[5.5.0.05,9 .03,11]dodecane (1) with n-butyl nitrite or ammonium cerium nitrate results in novel C(1)-C(7) oxidative cleavage to give 1,3,4,5,7,8-hexabenzyl-cis-cisoid-cis-hexahydro-1H, 5H-diimidazolinium[4,5-b:4′,5′-e]pyrazine dinitrate (2).

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Guan, X. P., Yan, H., Sun, J. G., & Yu, Y. Z. (1999). Novel carbon-carbon bond oxidative cleavage of hexabenzyl-hexaazaisowurtzitane by n-BuONO and (NH4)2Ce(NO3)6. Molecules, 4(3), 69–72. https://doi.org/10.3390/40300069

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