Sequential Template Decomposition to Adjust the Performance of Imperfect Zeolite BEA Membranes

Abstract

Zeolite membranes offer superior thermal, chemical, and mechanical stability compared to polymeric membranes. However, it is still a challenge to prepare completely defect-free membranes without any intercrystalline voids, which is necessary for gas separation processes. In this study zeolite beta (*BEA) membranes on stainless-steel supports were prepared by applying the multiple in situ crystallization technique. The membranes were used as a model system to systematically study the decomposition of the organic structure directing agent tetraethylammoniumhydroxide (TEA-OH). It was evaluated if the organic decomposition products of TEA-OH can be used for enhancing the membranes selectivity. Post-treatment experiments have been carried out to adjust surface properties and pore size dimensions in the zeolitic membrane layer. The results show that membranes calcined at lower temperatures exhibit a higher gas selectivity.