Bis[squaramido]ferrocenes as electrochemical sulfate receptors

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Abstract

1,1′-Bis[squaramido]ferrocenes (FcSq2) are introduced as electrochemically active scaffolds for sulfate recognition. FcSq2 display high sulfate-binding affinity and selectivity in aqueous DMSO mixtures. Among tested anions, sulfate elicits a unique electrochemical response in FcSq2, enabling selective detection.

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Lane, J. D. E., Greenwood, W. J. H., Day, V. W., Jolliffe, K. A., Bowman-James, K., & Adriaenssens, L. (2022). Bis[squaramido]ferrocenes as electrochemical sulfate receptors. New Journal of Chemistry, 46(38), 18119–18123. https://doi.org/10.1039/d2nj03951f

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