Thermodynamic stability and critical points in multicomponent mixtures with structured interactions

Abstract

Theoretical work has shed light on the phase behavior of idealized mixtures of many components with random interactions. However, typical mixtures interact through particular physical features, leading to a structured, nonrandom interaction matrix of lower rank. Here, we develop a theoretical framework for such mixtures and derive mean-field conditions for thermodynamic stability and critical behavior. Irrespective of the number of components and features, this framework allows for a generally lower-dimensional representation in the space of features and proposes a principled way to coarse-grain multicomponent mixtures as binary mixtures. Moreover, it suggests a way to systematically characterize different series of critical points and their codimensions in mean-field. Since every pairwise interaction matrix can be expressed in terms of features, our work is applicable to a broad class of mean-field models.