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Porous organic-inorganic assemblies constructed from Keggin polyoxometalate anions and calix[4]arene-Na+ complexes: Structures and guest-sorption profiles

Angewandte Chemie - International Edition (2004) 43(20) 2702-2705
DOI: 10.1002/anie.200453693
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Abstract

Amphiphilic pore walls facilitate reversible sorption of short-chain alcohols by the 1D microporous organic-inorganic hybrid [1-Na] 3[PW12O40] assembled from calix[4]-arene- Na+ complex 1-Na+ (R1 = R2 = H) and the polyoxotungstate anion [PW12O40]3-. The analogous assembly formed with 2-Na+ (R1 = tBu, R 2 = CH2CO2Et) has a 3D microporous architecture.

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Ishii, Y., Takenaka, Y., & Konishi, K. (2004). Porous organic-inorganic assemblies constructed from Keggin polyoxometalate anions and calix[4]arene-Na+ complexes: Structures and guest-sorption profiles. Angewandte Chemie - International Edition, 43(20), 2702–2705. https://doi.org/10.1002/anie.200453693

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