Comparison and applicability of Agilent EMR-Lipid and Captiva EMR-Lipid Sorbents in QuEChERS method for food analysis

Abstract

Agilent’s innovative EMR-Lipid and Captiva EMR- Lipid sorbents efficiently replace the traditional QuEChERS d-SPE clean-up products in selective lipid removal from fatty matrices, thus improving instrumental analytical reproducibility, reliability, and long-term use. These products have dual functionality; a hydrophobic interaction between the sorbent with long aliphatic lipid chains of the matrices, which allows for complete lipid retention, and a size exclusion property that does not retain analytes, thus this maximizes, in principle, analyte recovery in any sample. As most of the analytes under study were polar or not highly nonpolar and had a relatively large size, the examination of small-sized nonpolar or less polar compounds is necessary to check for partial retention by the sorbents and if any, further precautions should be taken when using these sorbents. These queries are answered in our present communication concerning the analytes Trifluralin (logP: 5.27), Fipronil (logP: 4.0), and Clenbuterol (logP: 2.63).