A novel profluorescent paramagnetic diaza-crown ether: Synthesis, characterization and alkaline metal-ion complexation

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Abstract

Starting from Kryptofix 22 two different branches were covalently attached through the nitrogen atoms, one containing a fluorescent moiety and the other the stable free radical TEMPO. The novel derivative exhibits fluorescence and paramagnetic properties, while the diaza-crown part ensures the affinity for alkaline metal-ions.

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Coman, A. G., Stavarache, C., Paun, A., Popescu, C. C., Hǎdade, N. D., Ionita, P., & Matache, M. (2019). A novel profluorescent paramagnetic diaza-crown ether: Synthesis, characterization and alkaline metal-ion complexation. RSC Advances, 9(11), 6078–6083. https://doi.org/10.1039/c8ra09828j

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