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Spin-crossover behavior of hofmann-type-like complex Fe(4,4’-bipyridine)Ni(Cn)4¨ nH2O depending on guest species

Magnetochemistry (2016) 2(1)
DOI: 10.3390/magnetochemistry2010008
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Abstract

A newly prepared metal complex Fe(4,4’-bipyridine)Ni(CN)4¨ nH2O, which was estimated to have a structure similar to the Hofmann-type clathrate host, changed its color from orange to deep orange and yellow on exposure to ethanol and acetone vapor, respectively, and the respective samples showed thermally induced two-step and one-step spin transitions.

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Hosoya, K., Nishikiori, S. I., Takahashi, M., & Kitazawa, T. (2016). Spin-crossover behavior of hofmann-type-like complex Fe(4,4’-bipyridine)Ni(Cn)4¨ nH2O depending on guest species. Magnetochemistry, 2(1). https://doi.org/10.3390/magnetochemistry2010008

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