Innovative application of magnetically modified bovine horn as a natural keratin resource in the role of value-added organocatalyst

Abstract

This study presents the conversion of bovine horn powder (BHP) as an available and low-cost waste material to a value-added highly recyclable catalyst. This green catalyst was prepared through the immobilization of BHP, as a natural keratin resource, on the magnetic Fe3O4 nanoparticles. The successful preparation of the catalyst was fully investigated using Fourier transform infrared, X-ray diffraction, and energy-dispersive X-ray spectroscopies as well as field emission scanning electron microscopy, vibrating sample magnetometry, and thermogravimetry. The catalytic efficiency of the prepared magnetic organocatalyst was evaluated in the synthesis of a large series of amide derivatives through the solvent-free transamidation reaction of different amides and amines with yields of 75-96%.