Tandem catalysts for the selective hydrogenation of butadiene with hydrogen generated from the decomposition of formic acid

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Abstract

We report for the first time the selective hydrogenation of 1,3-butadiene to butene using formic acid as the hydrogen source with 1 wt% Pd/carbon in a continuous flow reactor. The catalytic results show that the selectivity is even higher when formic acid is used compared to gas hydrogen.

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Carrales-Alvarado, D. H., Dongil, A. B., Guerrero-Ruiz, A., & Rodríguez-Ramos, I. (2021). Tandem catalysts for the selective hydrogenation of butadiene with hydrogen generated from the decomposition of formic acid. Chemical Communications, 57(53), 6479–6482. https://doi.org/10.1039/d1cc01954f

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