1,5-Bis(2-methylphenyl)-3-nitroformazan

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Abstract

In the title compound, C15H15N5O 2, the nitro O atoms are disordered over two sets of sites with an occupancy ratio of 0.75 (4):0.25 (4). Amine-imine tautomerism is observed in the formazan group. This was evident from the similar C - N bond distances in the formazan [1.319 (2) and 1.332 (3) Å], as well as the distribution of the imine proton in the Fourier difference map which refined to a 0.53 (3):0.47 (3) ratio. C - H⋯O and π-π interactions [centroid-centroid distances = 3.4813 (1) and 3.3976 (1) Å] are observed in the crystal packing.

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von Eschwege, K. G., Hosten, E. C., & Muller, A. (2012). 1,5-Bis(2-methylphenyl)-3-nitroformazan. Acta Crystallographica Section E: Structure Reports Online, 68(2). https://doi.org/10.1107/S1600536812001171

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