Abstract
Reduction of scandium nitride clusterfullerene, Sc3N@Ih-C80, by sodium fluorenone ketyl in the presence of cryptand[2,2,2] allows the crystallization of the {cryptand[2,2,2](Na+)}2(Sc3N@Ih-C80-)2·2.5C6H4Cl2 (1) salt. The Sc3N@Ih-C80- radical anions are dimerized to form single-bonded (Sc3N@Ih-C80-)2 dimers.
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APA
Konarev, D. V., Zorina, L. V., Khasanov, S. S., Popov, A. A., Otsuka, A., Yamochi, H., … Lyubovskaya, R. N. (2016). A crystalline anionic complex of scandium nitride endometallofullerene: Experimental observation of single-bonded (Sc3N@: I h-C80-)2 dimers. Chemical Communications, 52(71), 10763–10766. https://doi.org/10.1039/c6cc05550h
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