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Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre

Dalton Transactions (2018) 47(28) 9237-9240
DOI: 10.1039/c8dt01997e
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Abstract

We report a trinuclear mixed-valence {CoIICoIII2} complex, where the CoII centre adopts a trigonal bipyramidal geometry, leading to a large, easy-plane magnetic anisotropy and field-induced slow magnetic relaxation with a Raman-like relaxation process.

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Collet, A., Craig, G. A., Heras Ojea, M. J., Bhaskaran, L., Wilson, C., Hill, S., & Murrie, M. (2018). Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre. Dalton Transactions, 47(28), 9237–9240. https://doi.org/10.1039/c8dt01997e

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