Synthesis of nanocrystals of Zr-based metal-organic frameworks with csq-net: Significant enhancement in the degradation of a nerve agent simulant

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Abstract

The synthesis of nano-sized particles of NU-1000 (length from 75 nm to 1200 nm) and PCN-222/MOF-545 (length from 350 nm to 900 nm) is reported. The catalytic hydrolysis of methyl paraoxon was investigated as a function of NU-1000 crystallite size and a significant enhancement in the rate was observed for the nano-sized crystals compared to microcrystals.

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Li, P., Klet, R. C., Moon, S. Y., Wang, T. C., Deria, P., Peters, A. W., … Farha, O. K. (2015). Synthesis of nanocrystals of Zr-based metal-organic frameworks with csq-net: Significant enhancement in the degradation of a nerve agent simulant. Chemical Communications, 51(54), 10925–10928. https://doi.org/10.1039/c5cc03398e

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