Chemoselective Hydrogen Transfer Reduction of Unsaturated Ketones to Allylic Alcohols with Solid Zr and Hf Catalysts

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Abstract

α,β-Unsaturated ketones were reduced to allylic alcohols with high chemo- and diastereoselectivity, using Zr and Hf compounds heterogenised on mesoporous molecular sieves.

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De Bruyn, M., De Vos, D. E., & Jacobs, P. A. (2002). Chemoselective Hydrogen Transfer Reduction of Unsaturated Ketones to Allylic Alcohols with Solid Zr and Hf Catalysts. Advanced Synthesis and Catalysis, 344(10), 1120–1125. https://doi.org/10.1002/1615-4169(200212)344:10<1120::AID-ADSC1120>3.0.CO;2-4

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