Structural, magnetic and optical properties of disordered double perovskite Gd2CoCrO6 nanoparticles

Abstract

We have synthesized disordered double perovskite Gd2CoCrO6 (GCCO) nanoparticles with an average particle size of 71 ± 3 nm by adopting a citrate sol-gel method to investigate their structural, magnetic, and optical properties. Rietveld refinement of the X-ray diffraction pattern showed that GCCO is crystallized in a monoclinic structure with space group P21/n, which is further confirmed by Raman spectroscopic analysis. The absence of perfect long-range ordering between Co and Cr ions is confirmed by the mixed valence states of Co and Cr. A Néel transition was observed at a higher temperature of TN = 105 K compared to that of an analogous double perovskite Gd2FeCrO6 due to a greater degree of magnetocrystalline anisotropy of Co than Fe. Magnetization reversal (MR) behavior with a compensation temperature of Tcomp = 30 K was also observed. The hysteresis loop obtained at 5 K exhibited the presence of both ferromagnetic (FM) and antiferromagnetic (AFM) domains. Super-exchange and Dzyaloshinskii-Moriya (DM) interactions between various cations via oxygen ligands are responsible for the observed FM or AFM ordering in the system. Furthermore, UV-visible and photoluminescence spectroscopy demonstrated the semiconducting nature of GCCO with a direct optical bandgap of 2.25 eV. The Mulliken electronegativity approach revealed the potential applicability of GCCO nanoparticles in photocatalytic H2 and O2 evolution from water. Due to a favorable bandgap and potentiality as a photocatalyst, GCCO can be a promising new member of double perovskite materials for photocatalytic and related solar energy applications.