Abstract
The selectivity of supported gold catalysts in aerobic oxidation of cyclohexene under solvent-free conditions without addition of a radical initiator was tuned by either WO3 or the metal-organic framework MIL-101, used as a support/co-catalyst. WO3 was found to promote the formation of cyclohexene oxide via reaction of cyclohexenyl hydroperoxide with cyclohexene, while MIL-101 catalysed conversion of cyclohexenyl hydroperoxide to 2-cyclohexen-1-one. © 2014 The Royal Society of Chemistry.
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CITATION STYLE
Ovoshchnikov, D. S., Donoeva, B. G., Williamson, B. E., & Golovko, V. B. (2014). Tuning the selectivity of a supported gold catalyst in solvent- and radical initiator-free aerobic oxidation of cyclohexene. Catalysis Science and Technology, 4(3), 752–757. https://doi.org/10.1039/c3cy01011b
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