Abstract
The crystal structures of Co2P and Ru2P were refined by using single-crystal methods. Both phosphides crystallize in the C 23 structure type. A structural comparison with related phosphides and silicides is given. Co2P has an extended homogeneity range at higher temps., the P-rich limit at 1000 Deg corresponds to the formula Co1.94P. There are evidences that the widening of the homogeneity range is connected with random vacancies on metal atom sites.
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CITATION STYLE
APA
Rundqvist, S., Hede, A., Rundqvist, S., Varde, E., & Westin, G. (1960). The Structures of Co2P, Ru2P, and Related Phases. Acta Chemica Scandinavica, 14, 1961–1979. https://doi.org/10.3891/acta.chem.scand.14-1961
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