Abstract
An unprecedented reaction: Dinitrogen pincer Rh complexes react with azines in a moderately catalytic fashion by "nonsymmetrical" N-N bond cleavage to the corresponding nitriles and imines (see scheme).
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APA
Cohen, R., Rybtchinski, B., Gandelman, M., Shimon, L. J. W., Martin, J. M. L., & Milstein, D. (2003). Novel azine reactivity: Facile N-N bond cleavage, C-H activation, and N-N coupling mediated by RhI. Angewandte Chemie - International Edition, 42(17), 1949–1952. https://doi.org/10.1002/anie.200250571
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